Unit-1: Classical Statistical Mechanics
(a) Macrostate & Microstate, Elementary Concept of Ensemble and Ergodic Hypothesis,
Phase Space and Liouville theorem.
(b) Microcanonical ensemble, Postulate of Equal a-priori probabilities. Boltzmann hypothesis: Entropy and Thermodynamic Probability.
(c) Canonical ensemble, Partition Function, Thermodynamic Functions of an Ideal Gas, harmonic
oscillator, and paramagnetism, Classical Entropy Expression, Gibbs Paradox.
(d) Law of Equipartition of Energy, Applications to Specific Heat and its Limitations. Thermodynamic Functions of a Two-Energy Level System.
(e) Grand canonical ensemble. Application of ideal gas using grand canonical ensemble. chemical
potential
Unit-2: Systems of Identical particles
Collection of non-interacting identical particles. Occupation number and MB distribution, Composite system postulate and symmetry postulate of quantum mechanics (for a pair of particles only). Bosons and Fermions. Symmetric and Antisymmetric wave functions. state counting for bosons and fermions.
Unit-3: Bose-Einstein Statistics
B-E distribution law. Bose Einstein condensation and properties of liquid He IV (qualitative description only).
Unit-4: Fermi-Dirac Statistics
Fermi-Dirac Distribution Law. Thermodynamic functions of strongly Degenerate Fermi Gas, Fermi Energy.